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Importing and Exporting (matchms 0.33.1)

skills/matchms/references/importing_exporting.md

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Importing and Exporting (matchms 0.33.1)

Use this reference for file-format selection, return types, streaming behavior, and safe serialization. The authoritative APIs are the matchms importing and exporting packages.

Recommended Entry Points

Use extension-based helpers for ordinary local files:

python
from matchms.importing import load_spectra
from matchms.exporting import save_spectra

spectra = list(load_spectra("library.msp"))
save_spectra(spectra, "cleaned.mgf")

load_spectra() supports mzML, mzXML, MGF, MSP, JSON, and .pickle. save_spectra() supports MGF, MSP, JSON, and .pickle in 0.33.1. Use format-specific functions when you need an MS level, file-like MGF input, mzSpecLib output, or precise writer options.

save_spectra() refuses to overwrite an existing output unless append=True, and append mode is restricted to MGF and MSP. This makes it safer than direct writers, whose MGF/MSP defaults are append mode.

Import Matrix

MGF

python
from matchms.importing import load_from_mgf

spectra = list(load_from_mgf("queries.mgf"))

Signature:

text
load_from_mgf(filename: str | Path | TextIO,
              metadata_harmonization: bool = True) -> Generator[Spectrum]

MGF is a practical interchange format for centroided MS/MS spectra and supports streaming iteration. It can also read an already-open text handle:

python
with open("queries.mgf", encoding="utf-8") as handle:
    spectra = list(load_from_mgf(handle))

MSP

python
from matchms.importing import load_from_msp

library = list(load_from_msp("library.msp"))

Signature:

text
load_from_msp(filename: str,
              metadata_harmonization: bool = True) -> Generator[Spectrum]

MSP is common for reference libraries. Matchms 0.29+ includes support for GOLM-style MSP data, but source metadata still varies substantially by library.

mzML and mzXML

python
from matchms.importing import load_from_mzml, load_from_mzxml

ms2 = list(load_from_mzml("sample.mzML", ms_level=2))
ms1 = list(load_from_mzxml("legacy.mzXML", ms_level=1))

Signatures:

text
load_from_mzml(filename: str | Path, ms_level: int = 2,
               metadata_harmonization: bool = True) -> Generator[Spectrum]
load_from_mzxml(filename: str | Path, ms_level: int = 2,
                metadata_harmonization: bool = True) -> Generator[Spectrum]

These readers select one MS level. For chromatograms, binary arrays beyond the Spectrum abstraction, vendor-specific metadata, or more complex raw-data parsing, use pyteomics, pymzML, or pyopenms.

JSON

python
from matchms.importing import load_from_json

spectra = load_from_json("spectra.json")

Signature:

text
load_from_json(filename: str,
               metadata_harmonization: bool = True) -> list[Spectrum]

The JSON reader returns a list, not a generator. It supports matchms JSON and GNPS-style spectral-library JSON and skips spectra with zero peaks.

Metabolomics USI

python
from matchms.importing import load_from_usi

spectrum = load_from_usi(
    "mzspec:GNPS:GNPS-LIBRARY:accession:CCMSLIB00000424840"
)

Signature:

text
load_from_usi(
    usi: str,
    server: str = "https://metabolomics-usi.gnps2.org",
    metadata_harmonization: bool = True,
)

USI loading makes an external network request. Preserve the USI, resolver URL, retrieval date, and retrieved metadata with analysis outputs. Handle service failures and None/invalid responses rather than assuming availability.

Pickle

python
from matchms.importing import load_from_pickle

spectra = load_from_pickle("trusted-cache.pickle", metadata_harmonization=True)

The metadata_harmonization argument is required in 0.33.1.

Security: Python pickle is executable serialization. Loading an untrusted pickle can run arbitrary code. Use MGF, MSP, JSON, or mzSpecLib for exchanged or downloaded data. Restrict pickle to trusted, local, reproducible caches.

Generator and Memory Semantics

MGF, MSP, mzML, and mzXML readers yield generators. JSON and pickle readers return lists. Converting a generator with list(...) loads all spectra and peak arrays into memory.

Pairwise scoring requires materialized collections. Before scoring, estimate:

python
pair_count = len(references) * len(queries)

For preprocessing-only MGF/MSP workflows, stream one spectrum at a time:

python
from pathlib import Path

from matchms.exporting import save_spectra
from matchms.filtering import default_filters, normalize_intensities
from matchms.importing import load_from_mgf

output = Path("cleaned.mgf")
if output.exists():
    raise FileExistsError(output)

first_write = True
for spectrum in load_from_mgf("large.mgf"):
    spectrum = default_filters(spectrum)
    spectrum = normalize_intensities(spectrum)
    if spectrum is None:
        continue
    save_spectra([spectrum], str(output), append=not first_write)
    first_write = False

For many spectra, writing larger batches is usually faster than one record per call.

Metadata Harmonization

The importers default to metadata_harmonization=True. This normalizes source keys to matchms conventions while constructing each Spectrum.

Keep harmonization enabled for cross-source comparisons. Disable it only when:

  • exact source keys must be preserved;
  • you have a documented custom normalization layer; or
  • you are investigating an importer/harmonization issue.

When source fidelity matters, retain the original file and export a metadata audit before applying repair filters.

Export Matrix

Generic writer

python
from matchms.exporting import save_spectra

save_spectra(spectra, "output.mgf", export_style="matchms")
save_spectra(spectra, "output.msp", export_style="nist")
save_spectra(spectra, "output.json", export_style="gnps")

Signature:

text
save_spectra(spectra, file: str,
             export_style: str = "matchms",
             append: bool = False) -> None

Supported export styles are matchms, massbank, nist, riken, and gnps. Not every source metadata field has a lossless representation in every target format. Reopen converted data and compare identifiers, precursor values, peak counts, and representative peaks.

Direct MGF writer

text
save_as_mgf(spectra, filename, export_style="matchms", file_mode="a")

The direct writer's default is append mode. Pass file_mode="w" when creating a fresh output, or prefer save_spectra() for overwrite protection.

Direct MSP writer

text
save_as_msp(spectra, filename, write_peak_comments=True,
            mode="a", style="matchms", peak_sep="\t")

The direct writer also defaults to append mode. Peak comments can be retained when supported by the input and output style.

JSON writer

text
save_as_json(spectra, filename, export_style="matchms")

JSON is portable and preserves matchms-oriented structured metadata better than plain text library formats, but it is not a raw-data archive.

mzSpecLib writer

python
from matchms.exporting import save_as_mzspeclib

save_as_mzspeclib(spectra, "library.mzspeclib.txt")

save_as_mzspeclib() exports a list of spectra through psims. Validate the result with the downstream mzSpecLib consumer because metadata requirements can be stricter than MGF/MSP.

Pickled spectra

The generic writer recognizes a .pickle extension:

python
save_spectra(spectra, "trusted-cache.pickle")

Use the full .pickle suffix; .pkl is not recognized by save_spectra() in 0.33.1. Pickle is Python-specific, version-sensitive, and unsafe for untrusted inputs.

Score Serialization

A Scores object has dedicated serializers:

python
scores.to_json("scores.json")
scores.to_pickle("scores.pickle")

Prefer JSON for exchange. Pickled Scores objects have the same arbitrary-code execution risk as pickled spectra.

Load score JSON using matchms's score loader rather than manually reconstructing the sparse stack. Confirm exact loader names with the installed version because the importing package exposes both current and compatibility aliases.

Conversion Pattern

python
from matchms.exporting import save_spectra
from matchms.importing import load_from_mzml

spectra = list(load_from_mzml("sample.mzML", ms_level=2))
save_spectra(spectra, "sample-ms2.mgf")

roundtrip = list(load_spectra("sample-ms2.mgf"))
assert len(roundtrip) == len(spectra)
for before, after in zip(spectra[:10], roundtrip[:10], strict=True):
    assert len(before.peaks) == len(after.peaks)

Do not assume conversion preserves all acquisition metadata. MGF and MSP are spectral interchange/library formats, not lossless replacements for mzML.

Output Validation Checklist

  • Reopen the output with matchms or the intended downstream consumer.
  • Compare spectrum count and non-empty peak count.
  • Compare precursor m/z, charge, ion mode, and identifiers.
  • Compare m/z and intensity arrays for representative records.
  • Confirm the chosen export style and append/overwrite mode.
  • Preserve the original source alongside converted data.
  • Never load exchanged pickle data.